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Alkane Nomenclature
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Topic: Alkane Nomenclature (Read 124 times)
susanbamboozlin
Labrat
Posts: 2
Alkane Nomenclature
«
on:
January 27, 2010, 08:20:55 PM »
I am having some trouble with naming alkanes. I think I did the first two problems correctly, but I am not sure. I am having some trouble with the third one, and would greatly appreciate any help you can offer. I would like to have an explanation along with the answer so I can see what I did wrong! Thanks very much!
1. (CH3)2CHCH(CH3)2
4-carbon chain makes it butane
the branches at both C2 and C3 are methyl
so the name is 2,3-dimethylbutane
CH2Ch2CH2CH3
l
CH3CH2CH2CHCH2C--H
l l
CH3CH2 H
6-carbon chain makes it hexane
branch at C2 is butyl
branch at C3 is ethyl
so the name is 2-butyl-3-ethylbutane.
3. This is the one I am very unsure of:
CH3 H
l l
CH3CH2CH2CH2--C--C--CH2CH3
l l
CH2 CH3
l
CH3
8-carbon chain= octane
branch at C3 is methyl
branches at 4C are methyl and ethyl
That is where I get stuck on the name. Is it 4-ethyl-4,3-dimethyloctane??
Thank you very much for your input!
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freezard7734
Labrat
Posts: 16
Re: Alkane Nomenclature
«
Reply #1 on:
January 28, 2010, 08:31:33 AM »
The first one is correct. However, in the second one, you should use the
longest
C-branch as the base. There is a chain much longer than 6 carbons.
Actually, your third one seems fine...
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bhavna
Labrat
Posts: 6
Re: Alkane Nomenclature
«
Reply #2 on:
February 17, 2010, 09:52:29 PM »
Frist one is correct. Second ans should be, by selecting longest C chain which is decane; so it should be named as 4 ethly decane.
Thrid ans should be 3,4-dimethyl-4-ethyloctane, coz we should always select frist longest C chain & then numbering for groups should be in ascending orders as 1,2,3... & not as 3,2
«
Last Edit: February 17, 2010, 09:59:42 PM by bhavna
»
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