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Author Topic: Thermochemistry-Calculating q, w, and ΔE.  (Read 326 times)
xgiapet12x
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« on: September 29, 2008, 10:50:44 PM »

A balloon filled with 54.1 mol helium has a volume of 1212. L at 0.0°C and 1.00 atm pressure. The temperature of the balloon is increased to 33.0°C as it expands to a volume of 1359. L, the pressure remaining constant. Calculate q, w, and ΔE in kJ for the helium in the balloon. (The molar heat capacity for helium gas is 20.8 J/°C·mol.)

I was able to figure out q:
q= n cp ΔT= (54.1)(20.8 )(33.0-0.0)=37134 J/1000=37.1 kJ

I know that in order to find ΔE you need to add q and w, but i don't know how to find w. Help?   
 
 
 
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where is this 1
kyle1990
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« Reply #1 on: September 30, 2008, 07:03:30 PM »

w=-P X change in volume

p is the pressure
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"Theories are nets cast to catch what we call 'the world': to rationalize, to explain, and to master it. We endeavor to make the mesh ever finer and finer."
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xgiapet12x
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« Reply #2 on: October 01, 2008, 08:54:08 PM »

w= (-1.00 atm)(1359 L - 1212 L)=-147

is this right?
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kyle1990
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« Reply #3 on: October 01, 2008, 09:31:10 PM »

yes
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"Theories are nets cast to catch what we call 'the world': to rationalize, to explain, and to master it. We endeavor to make the mesh ever finer and finer."
-Karl Popper
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