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Author Topic: isotopes and mass spectrums  (Read 214 times)
roseybabyy
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« on: September 22, 2008, 08:04:57 PM »

I'm having trouble with this problem. I don't even know where to start.

"Gallium arsenide, GaAs, has gained widespread use in semiconductor devices that convert light and electrical signals in fiberoptic communications systems. Gallium consists of 60% 69Ga and 40% 71Ga. Arsenic has only one naturally occurring isotope, 75As. Gallium arsenide is a polymeric material, but its mass spectrum shows fragments with the formulas GaAs and Ga2As2. What would the distribution of peaks look like for these two fragments?"

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Otis
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« Reply #1 on: September 27, 2008, 06:13:19 PM »

Wow, Lets help out.

Given your information you can only have two possible product with regard to isotopes 69Ga75As and 71Ga75As. You would have peaks at 144 and 146 with a relative size of 6 to 4 respectively (just like the percentages)

Otis
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valdorod
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« Reply #2 on: September 28, 2008, 03:39:40 AM »

Wow, Lets help out.

Given your information you can only have two possible product with regard to isotopes 69Ga75As and 71Ga75As. You would have peaks at 144 and 146 with a relative size of 6 to 4 respectively (just like the percentages)

Otis

For this case the spectrum should look like this


For the second fragment the Ga2As2 you have two choices for Ga and one choice for As

This gives us the following posibilities
69Ga271As2 ,69Ga71Ga71As2 , and 71Ga271As2 resulting in a triplet. 
 
First assuming that the first Ga is Ga-69, a 60% chance.  The second Ga can either be Ga-69 a 60% chance or Ga-71 40% chance

The probabilities are
 
Ga-69 and Ga-69 = 0.6 x 0.6 = 0.36
Ga-69 and Ga-71 = 0.6 x 0.4 = 0.24

Second we assume that the first Ga is Ga-71 then we have

Ga-71 and Ga-69 = 0.4 x 0.6 = 0.24
Ga-71 and Ga-71 = 0.4 x 0.4 = 0.16

two of the choices above are the same, so we add their probabilities and we have

69Ga271As2 ,= 0.36

69Ga71Ga71As2 or 71Ga69Ga71As2 = 0.24 + 0.24 = 0.48

71Ga271As2 = 0.16

So the triplet has the smallest peak at the highest mass (71Ga271As2)
the largest peak at the middle mass (69Ga71Ga71As2 or 71Ga69Ga71As2)

the lightest species,69Ga271As2, has a peak intermediate in height.

and would look something like this

 

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Valdo

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Otis
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« Reply #3 on: September 28, 2008, 07:00:46 AM »

Oops, I missed the Ga2As2.

Otis
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