Wow, Lets help out.
Given your information you can only have two possible product with regard to isotopes 69Ga75As and 71Ga75As. You would have peaks at 144 and 146 with a relative size of 6 to 4 respectively (just like the percentages)
Otis
For this case the spectrum should look like this

For the second fragment the Ga
2As
2 you have two choices for Ga and one choice for As
This gives us the following posibilities
69Ga
271As
2 ,
69Ga
71Ga
71As
2 , and
71Ga
271As
2 resulting in a triplet.
First assuming that the first Ga is Ga-69, a 60% chance. The second Ga can either be Ga-69 a 60% chance or Ga-71 40% chance
The probabilities are
Ga-69 and Ga-69 = 0.6 x 0.6 = 0.36
Ga-69 and Ga-71 = 0.6 x 0.4 = 0.24
Second we assume that the first Ga is Ga-71 then we have
Ga-71 and Ga-69 = 0.4 x 0.6 = 0.24
Ga-71 and Ga-71 = 0.4 x 0.4 = 0.16
two of the choices above are the same, so we add their probabilities and we have
69Ga
271As
2 ,= 0.36
69Ga
71Ga
71As
2 or
71Ga
69Ga
71As
2 = 0.24 + 0.24 = 0.48
71Ga
271As
2 = 0.16
So the triplet has the smallest peak at the highest mass (
71Ga
271As
2)
the largest peak at the middle mass (
69Ga
71Ga
71As
2 or
71Ga
69Ga
71As
2)
the lightest species,
69Ga
271As
2, has a peak intermediate in height.
and would look something like this