homework help
dictionary
Downloads
Video
tutorials
tutors
My Chemistry Tutor
March 11, 2010, 08:13:56 PM
Welcome,
Guest
. Please
login
or
register
.
Did you miss your
activation email?
1 Hour
1 Day
1 Week
1 Month
Forever
Login with username, password and session length
News
:
Home
Help
Search
GoogleTagged
Login
Register
My Chemistry Tutor
>
Ask Chemistry Homework Questions
>
AP Chemistry
>
Choosing the best reducer/oxidyzer
Pages: [
1
]
« previous
next »
Print
Author
Topic: Choosing the best reducer/oxidyzer (Read 327 times)
pmennen
Labrat
Posts: 5
Choosing the best reducer/oxidyzer
«
on:
April 15, 2009, 12:26:05 PM »
How does one pick the best reducer?
For example, reaction "e" of the 1989 AP exam is:
"A solution of tin(II) chloride is added to an acidified
solution of potassium permanganate".
So it's pretty clear that permanganate is going to be the
oxidizer (getting reduced to (Mn)2+). Since Halide ions
can be strong reducers, I assumed the chloride would get
oxidized yielding the net ionic equation:
(Cl)- + (MnO4)- + H+ --> (Mn)2+ + Cl2 + H2O
However (Sn)2+ can also be a reducer (getting oxidized
to (Sn)4+) yielding the net ionic equation:
(Sn)2+ + (MnO4)- + H+ --> (Sn)4+ + (Mn)2+ + H2O
The answer sheet I have lists just the second one. Why
is that? Isn't my answer just as likely?
Similarly how does one pick the best oxidizer?
For example, reaction "c" of the same 1989 exam is:
"A stream of chlorine gas is passed through a solution
of cold, dilute sodium hydroxide".
So I figured chlorine can get oxidized by a reaction such as:
4(OH)- + Cl2 --> 2(ClO)- + 2H2O + 2e-
combined with the sodium ions being reduced giving the net
ionic equation:
OH- + Cl2 + Na+ --> (ClO)- + Na + H2O
However chlorine could be reduced as well as being oxidized
so the answer sheet gave the equation:
OH- + Cl2 --> (ClO)- + Cl- + H2O
But how would one know that this is more likely than my answer?
Thanks
~Paul
Logged
Text for Header
Powered by LivePerson
kyle1990
Global Moderator
Hero Member
Posts: 805
Re: Choosing the best reducer/oxidyzer
«
Reply #1 on:
April 15, 2009, 01:14:17 PM »
Refer to a standard reduction potential table. The table is read as reduction potentials. Everything in the left column is arranged in order of decreasing oxidizing capability from top to bottom. Notice that fluorine is the best oxidizer on the table and thus at the top of the list. On the right hand column, the strongest reducers are on the bottom and generally include the alkali/alkaline metals. It can get a bit confusing if you don't have the jargon straight.
You can see from the table that Sn2+ is a weaker oxidizing agent than MnO4- so MnO4- will be reduced because it is the stronger oxidizing agent and Sn2+ will become oxidized.
Logged
"Theories are nets cast to catch what we call 'the world': to rationalize, to explain, and to master it. We endeavor to make the mesh ever finer and finer."
-Karl Popper
Pages: [
1
]
Print
« previous
next »
Jump to:
Please select a destination:
-----------------------------
Ask Chemistry Homework Questions
-----------------------------
=> High School Chemistry
=> AP Chemistry
=> College Chemistry
=> Organic Chemistry
=> New Tutorials
-----------------------------
Ask Chemistry Lab Questions
-----------------------------
=> College Chemistry Labs
=> High School Chemistry Labs
Share this topic...
In a forum
(BBCode)
[url=http://www.mychemistrytutor.com/forums/index.php?topic=3653.0]Choosing the best reducer/oxidyzer[/url]
In a site/blog
(HTML)
Choosing the best reducer/oxidyzer
My Chemistry Tutor
Promote Your Page Too
Loading...