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Calculate delta G with partial pressure

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Author Topic: Calculate delta G with partial pressure  (Read 1502 times)
annfreakinpark
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« on: February 01, 2010, 12:37:12 PM »

Consider the reaction 2 NO2(g)--> N2O4(g).

Calculate ΔG at 298 K if the partial pressures of NO2 and N2O4 are 0.30 atm and 1.65 atm, respectively.


I know that I have to convert the atm to moles using the ideal gas law. But how can I find the moles without the volume?

Please help!



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kingchemist
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« Reply #1 on: February 01, 2010, 02:46:31 PM »
1

Kp = ppN2O4/(ppNO2)2 = 1.65/0.302

You can work out mole fraction from partial pressure.
Mole fraction NO2 = 0.30/(0.30+1.65)
Mole fraction N2O4 = 1.65/(0.30+1.65)

This will give the ratio of moles
hey
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'Chemistry is not just the study of matter; Chemistry is the study which matters!' - Kingchemist
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